Fuels Flashcards
All 32 cards in this deck
What is a hydrocarbon?
A compound that contains carbon and hydrogen only.
True or false? Ethanol, , is a hydrocarbon.
False. It contains oxygen as well as carbon and hydrogen, so it is not a hydrocarbon.
What is crude oil?
A complex mixture of hydrocarbons, whose molecules have carbon atoms in chains or rings. It is a finite resource.
Why is crude oil an important raw material?
It is a source of fuels and of feedstock for the petrochemical industry.
How does fractional distillation separate crude oil into fractions?
The crude oil is heated to a vapour and fed into a column that is hot at the bottom and cooler at the top. Each fraction condenses at the height matching its boiling point range: higher boiling points condense lower down.
Why does the viscosity of the fractions increase down a fractionating column?
The molecules are larger/longer (more carbons), so there are stronger intermolecular forces between them.
What is the kerosene fraction used for?
Fuel for aircraft (jets).
What is the diesel oil fraction used for?
Fuel for some cars and for trains (also lorries, tractors).
What is the fuel oil fraction used for?
Fuel for large ships and in some power stations.
What is the bitumen fraction used for?
Surfacing roads and roofs.
State two features of a homologous series.
They have the same general formula, and neighbouring compounds differ by . (Also: same functional group, similar chemical properties, a trend in physical properties.)
What is the general formula of the alkanes?
e.g. the alkane with 4 carbon atoms— with this gives .
Why are butane, , and pentane, , neighbouring members of the same homologous series?
They differ by , and they have the same general formula (both alkanes).
What are the products of the complete combustion of a hydrocarbon fuel?
Carbon dioxide and water, and energy is given out (the reaction is exothermic).
Why can incomplete combustion of a hydrocarbon produce carbon monoxide and carbon (soot)?
There is insufficient oxygen to oxidise all the carbon to carbon dioxide.
e.g.How does carbon monoxide behave as a toxic gas?
It reacts with haemoglobin in the blood, stopping oxygen being carried, so less oxygen reaches the brain. It is colourless and odourless, so hard to detect.
Give two problems caused by soot produced by incomplete combustion in fuel-burning appliances.
It can aggravate asthma/respiratory problems, and it makes buildings dirty.
How does burning a fuel that contains sulfur impurities lead to acid rain?
The sulfur impurity is oxidised to sulfur dioxide, which dissolves in rain water/clouds to form sulfuric acid.
Give two problems caused by acid rain.
It kills fish in lakes and kills trees. (It also damages buildings and causes breathing problems.)
Why are nitrogen oxides from engines described as pollutants?
They are acidic and toxic, and they lead to acid rain, which damages buildings and kills plants.
An impure hydrocarbon fuel is burned and the gases are passed through indicator solution, which shows an acidic gas. Which acidic gases are responsible?
Sulfur dioxide (from the sulfur impurity) and carbon dioxide.
Give two advantages of using hydrogen rather than petrol as a car fuel.
Burning it produces only water, so no carbon dioxide, carbon monoxide or sulfur dioxide; the supply can be renewable (made from water).
Give two disadvantages of using hydrogen rather than petrol as a car fuel.
It is hard to store and transport (very flammable gas, stored under pressure), and there are few filling stations; energy from fossil fuels is often used to make it.
Which common fuels are non-renewable fossil fuels, and where does each come from?
Petrol, kerosene and diesel oil from crude oil; methane from natural gas.
What does it mean to say a fuel is non-renewable?
It is used up much faster than it is formed, so the supply is finite and cannot be replaced.
What is cracking?
Breaking down larger, saturated hydrocarbon molecules (alkanes) into smaller, more useful ones, some of which are unsaturated (alkenes).
Why is cracking necessary?
The supply of long-chain fractions is greater than the demand, while demand for short-chain fuels such as petrol is high; cracking also makes useful alkenes.
True or false? All the products of cracking are alkanes.
False. Some products are unsaturated alkenes, such as .
What is the petrol fraction used for?
Fuel for cars.
What is the gases fraction from crude oil used for?
Domestic heating and cooking.
How are oxides of nitrogen formed when a fuel burns in an engine?
The engine gets very hot, and at these high temperatures nitrogen and oxygen from the air drawn in react with each other.
How does the boiling point change as alkane molecules get longer, and why?
It increases. Longer molecules have stronger intermolecular forces between them, so more energy is needed to overcome these forces.